Abstract
New quasi-one-dimensional bromo-bridged PdII-PdIV mixed-valence complexes with long chain alkylsufonates [Pd(en) 2][PdBr2(en)](CnH2n+1SO 3)4·2H2O (en = ethylene-diamine, n = 7, 8, 9, and 10) were synthesized. With increasing alkyl-chain length (n) of the counter anions, the PdII⋯PdIV distances decreased, indicating that the oxidation states of the Pd atoms are close to the Pd III state. © 2007 The Chemical Society of Japan.
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CITATION STYLE
Arakawa, H., Kawakami, D., Takaishi, S., Kajiwara, T., Miyasaka, H., Sugiura, K. I., … Okamoto, H. (2007). Tuning of electronic structures of quasi-one-dimensional bromo-bridged PdII-PdIV mixed-valence complexes by substituting counter anions. Bulletin of the Chemical Society of Japan, 80(1), 189–191. https://doi.org/10.1246/bcsj.80.189
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