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Hypervalent zinc(I) complexes with an NNNN- macrocycle: C–H bond activation across the zinc(I)–zinc(I) bond†

Chemical Communications (2024) 60(80) 11359-11362
DOI: 10.1039/d4cc04266b
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Abstract

Hetero- and homoleptic dinuclear zinc(i) complexes containing the macrocycle Me4TACD (N,N′,N′′,N′′′-1,4,7,10-tetramethylcyclododecane) were prepared; the heteroleptic complex [(Me4TACD)Zn-ZnCp*]+ reacted with activated hydrocarbons R-H (R = CH2CN, C=RCPh) to give the corresponding hydrocarbyl zinc(ii) complexes [(Me4TACD)ZnR]+.

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APA

Mahawar, P., Rajeshkumar, T., Spaniol, T. P., Maron, L., & Okuda, J. (2024). Hypervalent zinc(I) complexes with an NNNN- macrocycle: C–H bond activation across the zinc(I)–zinc(I) bond†. Chemical Communications, 60(80), 11359–11362. https://doi.org/10.1039/d4cc04266b

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