A New Method of Synthesis Carbon with Onion-Like Structure with High (10-13%) Content of Nitrogen from Pyridine

Abstract

The new method of pyridine pyrolysis is created, the some part of pyrolytic soot of which contains onion-similar carbon with high (10-13%) contents of nitrogen (or “pyridine carbon”). Nanoparticles of this “pyridine carbon” are formed only in a gas phase at the expense of reactions of polymerization and polycondensation of molecules of pyridine and by reactionary flow in a low-temperature zone of reactionary space are taken out. Onion-structures of the greater size and with the small contents of nitrogen (~1.0 %) together with nanotubes and filaments are products of heterogeneous reactions between carbon fragments of destruction of pyridine molecules, which mainly on the most high-temperature surface of quartz reactor are carried out. Nitrogen-containing fragments of a destruction of a molecule С 5 H 5 N mainly as НCN in a gas flow from sphere of reaction are removed. The growth of carbon nanostructures is realized at the expense of heterogeneous reactions but in absence of the metallic catalyst. The products were characterized by methods X-ray photoelectron and IR spectroscopy, scanning, transmission and high resolution transmission electron microscopy, X-ray diffraction and chemical analysis.