Cryovoltammetrically probing functional group reductive cleavage: Alkyl-sulfur versus aryl-sulfur bond cleavage in an alkyl naphthyl thioether under single electron-transfer is temperature switchable

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Abstract

A series of single electron-transfer (SET) reactions on a naphthyl thioether have shown that the reductive cleavage mechanism changes at low temperatures and this selectivity is proved using an electrochemical analysis that mimics the SET reaction conditions. © The Royal Society of Chemistry 2006.

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Paddon, C. A., Bhatti, F. L., Donohoe, T. J., & Compton, R. G. (2006). Cryovoltammetrically probing functional group reductive cleavage: Alkyl-sulfur versus aryl-sulfur bond cleavage in an alkyl naphthyl thioether under single electron-transfer is temperature switchable. Chemical Communications, (32), 3402–3404. https://doi.org/10.1039/b606638k

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