Temperature Estimation during Pulsed Laser Sintering of Silver Nanoparticles

Abstract

During the thermal sintering of metal nanoparticles (NPs) the process temperature plays the most important role in the outcome of the sintering results and the selection of a suitable substrate. Here, temperature calculation during pulsed laser sintering of silver (Ag) nanoparticles (NPs) inkjet-printed on glass substrates is presented. During the pulsed laser sintering of Ag NPs, a minimum line resistivity less than twice the bulk silver resistivity was obtained within around 52 s under a laser power of 276 mW. The temperature field during the pulsed laser sintering of Ag NPs was estimated via a three-dimensional numerical model in which a temperature-dependent thermal conductivity of Ag NPs was adopted. An algorithm for treating the thermal conductivity of the heated Ag NPs in a region by a previous laser shot was devised for the improvement of the temperature field estimation. A maximum temperature of approximately 204◦C over the Ag NPs line was obtained with a 276 mW laser power and a scanning speed of 135 µm/s.