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Relative Ortho-Directing Power of Fluorine, Chlorine and Methoxy Group for the Metalation Reaction in the Diazine Series. Diazines XXXV

Journal of Heterocyclic Chemistry (2003) 40(5) 855-860
DOI: 10.1002/jhet.5570400517
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Abstract

The regioselectivity of the metalation of 2-chloro-6-methoxypyrazine, 2-fluoro-6-methoxypyrazine and 3-fluoro-6-chloropyridazine was studied; the relative ortho-directing power was F > OMe > Cl.

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Toudic, F., Turck, A., Plé, N., Quéguiner, G., Darabantu, M., Lequeux, T., & Pommelet, J. C. (2003). Relative Ortho-Directing Power of Fluorine, Chlorine and Methoxy Group for the Metalation Reaction in the Diazine Series. Diazines XXXV. Journal of Heterocyclic Chemistry, 40(5), 855–860. https://doi.org/10.1002/jhet.5570400517

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