On the source of transfer of stereochemical information in ligands for Pd-catalyzed AAA reactions

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Abstract

Examination of a series of ligands for a Pd-catalyzed asymmetric allylic alkylation (AAA) suggests the importance of buttressing effects for creating chiral space for high enantioselectivity.

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Trost, B. M., Zambrano, J. L., & Richter, W. (2001). On the source of transfer of stereochemical information in ligands for Pd-catalyzed AAA reactions. Synlett, (SPEC. ISS), 907–909. https://doi.org/10.1055/s-2001-14663

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