Carbide clusterfullerene DyYTiC@C80 featuring three different metals in the endohedral cluster and its single-ion magnetism

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Abstract

Carbide clusterfullerene DyYTiC@C80-Ih with three different metal atoms in the endohedral cluster is obtained by arc-discharge synthesis with methane as reactive gas and is successfully isolated by HPLC. The compound shows single-molecule magnetism (SMM) with magnetic hysteresis below 8 K. The SMM properties of DyYTiC@C80 are compared to those of DySc2N@C80 and the influence of the central atom in the endohedral cluster is analyzed.

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Brandenburg, A., Krylov, D. S., Beger, A., Wolter, A. U. B., Büchner, B., & Popov, A. A. (2018). Carbide clusterfullerene DyYTiC@C80 featuring three different metals in the endohedral cluster and its single-ion magnetism. Chemical Communications, 54(76), 10683–10686. https://doi.org/10.1039/c8cc04736g

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