Diagnostics of CO concentration in gaseous mixtures at elevated pressures by resonance enhanced multi-photon ionization and microwave scattering

Abstract

In this work, a novel diagnostic technique for carbon monoxide (CO) number density measurements in a nitrogen buffer mixture at elevated pressures up to 5 bar was developed and tested. The technique utilizes 2 + 1 resonance enhanced multi-photon ionization (REMPI) of CO induced by a femtosecond laser pulse at 230.1 nm, followed by detection of the number of REMPI-induced electrons using the microwave scattering (MS) method (REMPI-MS technique). Dependences of the number of REMPI-generated electrons on CO number density and laser energy were measured and analyzed in conjunction with a four energy level model of the CO molecule. The number of REMPI-induced electrons scaled linearly with CO number density up to about 5 × 1018 cm-3 and was independent of the buffer gas pressure up to 5 bar. Higher CO number densities caused saturation onset associated with laser beam energy loss while travelling through the gaseous mixture due to two-photon absorption and photoionization. The number of REMPI-induced electrons was found to scale cubically with the laser pulse energy for the tested energy range of 8-20 μJ (intensity in the focal region about 7-18 GW/cm2), which is consistent with the operation regime where the number density of excited CO molecules increases throughout the laser pulse duration and does not saturate in time. The linear scaling region of the REMPI-MS signal can be used for a CO number density diagnostic after appropriate calibration of the system.