Electrocatalytic oxidation of sugars on silver-UPD single crystal gold electrodes in alkaline solutions

Abstract

A highly catalytic system for sugar oxidation in alkaline media is presented, for the first time, in which glucose oxidation takes place at ca. -0.44 V (vs. Ag|AgCl). Modification of Au(111) single crystal surface by under potential deposition (UPD) was carried out for a variety of metals and catalytic effect for sugar oxidation has been studied in 0.1 M NaOH. UPD of Ag ad-atoms on Au electrodes were of the best catalytic activity compared to other metals (Cu, Co, Ru, Cd, Ir, and Pt, etc.). For aldose type monosaccharide studied (glucose, mannose and xylose) as well as for aldose-containing disaccharides (maltose and lactose), one significant oxidation peak was obtained, however, no significant oxidation current was observed for disaccharides like sucrose. Gluconolactone and mannolactone gave no oxidation current at negative potentials at which glucose was oxidized, indicating no more than two-electron oxidation took place. With Ag ad-atoms coverage of ca. 0.3 monolayer leads to a positive catalytic effect expressed through a negative shift of ca. 0.14 V (glucose case) on the oxidation potential and a slight increase in peak current. At the Au(100) surface similar results to those at an Au(111) electrode were also observed. © 2003 Elsevier Science B.V. All rights reserved.