Scale breaks of suspended sediment rating in large rivers in Germany induced by organic matter

Abstract

Understanding the transport of suspended sediment and associated nutrients is of major relevance for sustainable sediment management aiming to achieve healthy river systems. Sediment rating curves are frequently used to analyze the suspended sediments and their potential sources and sinks. Here we use more than 750 000 measurements of suspended sediment concentrations (SSCs) and discharge (Q) collected at 62 gauging stations along 19 waterways in Germany based on the suspended sediment monitoring network of the German water and shipping authority, which started in the 1960s. Furthermore, we analyze more than 2000 measurements of the loss on ignition (LOI) of suspended matter at two stations along the rivers Moselle and Rhine to provide a proxy for the relative contributions of mineral load and organic matter. SSC and LOI are analyzed in terms of the power-law rating curve to identify discharge-dependent controls of suspended matter. Our results indicate that for most studied gauging stations, rating coefficients are not constant over the full discharge range, but there is a distinct break in the sediment rating curve, with specific SSC-Q domains above and below this break. The transition of the rating exponent likely results from increased supply of mineral suspended sediments from hillslope erosion at high flow and a shift of the organic matter sources from aquatic biomass-derived organic matter (i.e., high % LOI) at low flow, to mineral-associated organic matter with low % LOI eroded from hillslopes at higher flow. Based on these findings we developed a conceptual rating model for large ( > 10000 km2) and low-turbidity (SSC < 1000 mg L-1) rivers separating the mineral and organic fraction of the suspended matter in German waterways. This model allows evaluating the sources of the mineral and organic fraction of the suspended matter and facilitates new insights into the first-order control of discharge on the quality and quantity of suspended sediments.