The extra brillouin doublets and central peak of KTaO3 : Second sound vs. two-phonon difference scattering

Abstract

Low-T Brillouin spectra of the incipient ferroelectric KTaO3 exhibit a broad central peak (CP), and additional Brillouin doublets (BD), that can both be related to phonon-density fluctuations. On the basis of new high-resolution neutron data obtained of low-lying phonon branches, we analysed the phonon-kinetics mechanisms that are possibly the origin of these unusual features. Firstly, transverse acoustic (TA) phonons whose normal damping h faster than the BD frequency can produce hydrodynamic second sound. Secondly, two-phonon difference scattering from low damping thermal transverse phonons contribute to the spectra with either a sharp or a broader doublet, depending on the phonon group velocity and anisotropy of dispersion surfaces. The position of the observed sharp doublet is consistent with both mechanisms, but a comparison of the computed and experimental anisotropies favours the second process. © 2000 OPA (Overseas Publishers Association) N.V. Published by license under the Gordon and Breach Science Publishers imprint.