Static light scattering, ultraviolet-visible, and fluorescence spectroscopy from fluorescent methyl methacrylate/benzazole dye copolymers displaying an intramolecular proton-transfer mechanism in the electronically excited state

Abstract

The solution behavior of new copolymers of methyl methacrylate and benzazole dyes emitting fluorescence because of an intramolecular proton-transfer mechanism in the electronically excited state has been investigated by static light scattering, fluorescence spectroscopy, ultraviolet-visible, and gel permeation chromatography. In the dilute regime, with tetrahydrofuran (THF) and chloroform as solvents, the copolymers behave as typical polydisperse linear chains in good solvents. The analysis of the osmotic modulus for concentrated solutions in THF (c ≥ 60 g L-1) indicates the existence of an interchain association mechanism.