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Palladium-Catalyzed Decarboxylation-Carbonylation of Allylic Carbonates To Form β, γ-Unsaturated Estere

Journal of Organic Chemistry (1984) 49(8) 1341-1344
DOI: 10.1021/jo00182a005
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Abstract

Allyl alkyl carbonates undergo a smooth decarboxylation-carbonylation reaction to afford β,γ-unsaturated esters at 50 °C under atmospheric or low pressure of carbon monoxide and neutral conditions in the presence of palladium-phosphine complexes as catalysts. The reaction offers a very good method for the preparation of β,γ-unsaturated esters from allylic alcohols. © 1984, American Chemical Society. All rights reserved.

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Tsuji, J., Sato, K., & Okumoto, H. (1984). Palladium-Catalyzed Decarboxylation-Carbonylation of Allylic Carbonates To Form β, γ-Unsaturated Estere. Journal of Organic Chemistry, 49(8), 1341–1344. https://doi.org/10.1021/jo00182a005

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