Exploration of Carbon Dioxide Curing of Low Reactive Alkali-Activated Fly Ash

Abstract

In this paper, the effect of carbon curing procedure on low reactive fly ash alkali-activated pastes was investigated. Specimens were cured with pure carbon dioxide (CO2) gas for different curing times under 4 bar pressure. Chemical and physical characteristics of the geopolymer pastes were obtained from mass monitoring, titration test, XRD, FTIR and TGA-DTG analyses. Regarding the test results, after three days of CO2 curing, the highest CO2 uptake was obtained at 4.8 wt% of fly ash precursor, with carbon sequestration efficiency at 22.6%. The ratio of carbon dioxide absorbed as efflorescence to the total absorbed CO2 was measured. The results show that at early age, almost 50% of carbonated products appeared as efflorescence; however, by increasing the curing time, and after 3 days of curing, about 80% of carbon dioxide was stored in the matrix. It was found that, in all cases, carbonation curing was detrimental to the geopolymerization process due to a high amount of efflorescence and led to a reduction in the compressive strength. At 24 h and 3 days, the specimens showed a lower reduction in compressive strength in comparison to CO2 samples cured at 3 h, 6 h and 12 h. Regarding the XRD results, calcite was detected in the 24 h and 3 days specimens, which contributes to lower pore sizes due to a higher molar volume and production of silica gel that might participate in the polymerization processes and results in densified microstructures.