Directional picoantenna behavior of tunnel junctions formed by an atomic-scale surface defect

Abstract

Plasmonic nanoantennas have attracted much attention lately, among other reasons because of the directionality of light emitted by fluorophores coupled to their localized surface plasmon resonances. Plasmonic picocavities, i.e., cavities with mode volumes below 1 nm3, could act as enhanced antennas due to their extreme field confinement, but the directionality on their emission is difficult to control. In this work, we show that the plasmonic picocavity formed between the tip of a scanning tunneling microscope and a metal surface with a monoatomic step shows directional emission profiles and, thus, can be considered as a realization of a picoantenna. Electromagnetic calculations demonstrate that the observed directionality arises from the reshaping and tilting of the surface charges induced at the scanning tip due to the atomic step. Our results pave the way to exploiting picoantennas as an efficient way for the far-field probing and control of light-matter interactions below the nanoscale.