Impacts of meteorology and emissions on summertime surface ozone increases over central eastern China between 2003 and 2015

Abstract

Recent studies have shown that surface ozone (O3) concentrations over central eastern China (CEC) have increased significantly during the past decade. We quantified the effects of changes in meteorological conditions and O3 precursor emissions on surface O3 levels over CEC between July 2003 and July 2015 using the GEOS-Chem model. The simulated monthly mean maximum daily 8h average O3 concentration (MDA8 O3) in July increased by approximately 13.6%, from 65.5±7.9ppbv (2003) to 74.4±8.7ppbv (2015), comparable to the observed results. The change in meteorology led to an increase in MDA8 O3 of 5.8±3.9ppbv over the central part of CEC, in contrast to a decrease of about -0.8± 3.5ppbv over the eastern part of the region. In comparison, the MDA8 O3 over the central and eastern parts of CEC increased by 3.5±1.4 and 5.6±1.8ppbv due to the increased emissions. The increase in averaged O3 in the CEC region resulting from the emission increase (4.0±1.9ppbv) was higher than that caused by meteorological changes (3.1±4.9ppbv) relative to the 2003 standard simulation, while the regions with larger O3 increases showed a higher sensitivity to meteorological conditions than to emission changes. Sensitivity tests indicate that increased levels of anthropogenic non-methane volatile organic compounds (NMVOCs) dominate the O3 increase over the eastern part of CEC, and anthropogenic nitrogen oxides (NOix) mainly increase MDA8 O3 over the central and western parts and decrease O3 in a few urban areas in the eastern part. Budget analysis showed that net photochemical production and meteorological conditions (transport in particular) are two important factors that influence O3 levels over the CEC. The results of this study suggest a need to further assess the effectiveness of control strategies for O3 pollution in the context of regional meteorology and anthropogenic emission changes.