Impact of Charging and Charging Rate on Thermal Runaway Behaviors of Lithium-Ion Cells

Abstract

The present work carries out a series of thermal runaway experiments to explore the impact of charging and charging rate on the thermal runaway behaviors of lithium-ion cells, in which five charging rates (0 C, 0.5 C, 1 C, 2 C and 4 C) and three initial states of charge (SOC), i.e. 25%, 50% and 75% are included. The thermal runaway process of 18650 lithium-ion cells induced by over-heating usually consists of seven stages, and is accompanied with high-temperature, fire and toxicity risks. The internal morphology of cells and the micro features of cell materials are seriously damaged after thermal runaway. Charging aggravates the thermal runaway behavior of cells, which is further exhibited as the earlier occurrence of safety vent opening, gas releasing and thermal runaway. Moreover, the severity deteriorates as the charging rate increases (the larger the charging rate, the earlier and more severe the thermal runway), which may be ascribed to the growth of cell SOC and the decline of cell stability under charging. This phenomenon is especially apparent for the cell with a high initial SOC where a more dramatic-rising α (the advancement ratio of critical times for thermal runaway due to charging) is observed.