Does GLPT2 offer any actual benefit over conventional HF-MP2 in the context of double-hybrid density functionals?

Abstract

While the inclusion of the nonlocal correlation in fifth rung "double hybrid"functionals is definitely beneficial, one might rightfully ask whether its evaluation in the basis of Kohn-Sham (KS) orbitals has additional value compared to the use of Hartree-Fock reference orbitals (in a type of multilevel scheme). We have investigated this question for a very large and chemically diverse dataset, GMTKN55. We conclude that KS reference orbitals are undoubtedly beneficial, but the benefit is not as large as one might intuitively expect.