Pt Supported on Plasma-Chemical Titanium Nitride for Efficient Room-Temperature CO Oxidation

Abstract

Catalysts of carbon monoxide oxidation were synthesized by deposition of platinum on titanium nitride (TiN). Two substrates with an average particle size of 18 and 36 nm were obtained by hydrogen reduction of titanium tetrachloride in a stream of microwave plasma of nitrogen. The surface of the catalysts was studied by X-ray photoelectron spectroscopy (XPS). The CO oxidation rate on the 9‒15 wt.% Pt loaded TiN catalysts was found to be 120 times higher than that on platinum black with a specific surface of 30 m2/g. Such catalysts are promising for use in catalytic air purification systems.