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Palladium(II) Catalyzed cyclization-carbonylation-cyclization coupling reaction of (ortho-Alkynyl Phenyl) (Methoxymethyl) Sulfides using molecular oxygen as the terminal oxidant

Molecules (2016) 21(9)
DOI: 10.3390/molecules21091177
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Abstract

An efficient PdII /Pd0 -p-benzoquinone/hydroquinone-CuCl2 /CuCl catalyst system was developed that uses environmentally friendly molecular oxygen as the terminal oxidant to catalyze the cyclization-carbonylation-cyclization coupling reaction (CCC-coupling reaction) of (o-alkynyl phenyl) (methoxymethyl) sulfides.

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Shen, R., Kusakabe, T., Yatsu, T., Kanno, Y., Takahashi, K., Nemoto, K., & Kato, K. (2016). Palladium(II) Catalyzed cyclization-carbonylation-cyclization coupling reaction of (ortho-Alkynyl Phenyl) (Methoxymethyl) Sulfides using molecular oxygen as the terminal oxidant. Molecules, 21(9). https://doi.org/10.3390/molecules21091177

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