Dispersion of the local parameters of quasilocalized low-frequency vibrational modes in a low-temperature glass: Direct observation via single-molecule spectroscopy

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Abstract

Spectra of single tetra-tert-butylterrylene chromophore molecules embedded in an amorphous polyisobutylene matrix as microprobes were recorded. The individual temperature dependences of the spectral linewidths for the same single molecules (SMs) in a broad temperature interval (1.6

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Vainer, Y. G., Naumov, A. V., Bauer, M., & Kador, L. (2005). Dispersion of the local parameters of quasilocalized low-frequency vibrational modes in a low-temperature glass: Direct observation via single-molecule spectroscopy. Journal of Chemical Physics, 122(24). https://doi.org/10.1063/1.1929736

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