Experimental study of H2SO4 aerosol nucleation at high ionization levels

Abstract

One hundred and ten direct measurements of aerosol nucleation rate at high ionization levels were performed in an 8 m3 reaction chamber. Neutral and ion-induced particle formation from sulfuric acid (H2SO4) was studied as a function of ionization and H2SO4 concentration. Other species that could have participated in the nucleation, such as NH3 or organic compounds, were not measured but assumed constant, and the concentration was estimated based on the parameterization by Gordon et al. (2017). Our parameter space is thus [H2SO4] Combining double low line 4×106 - 3×107 cm-3, [NH3+ org] Combining double low line 2.2 ppb, T Combining double low line 295 K, RH Combining double low line 38 %, and ion concentrations of 1700-19 000 cm-3. The ion concentrations, which correspond to levels caused by a nearby supernova, were achieved with gamma ray sources. Nucleation rates were directly measured with a particle size magnifier (PSM Airmodus A10) at a size close to critical cluster size (mobility diameter of ∼ 1.4 nm) and formation rates at a mobility diameter of ∼4 nm were measured with a CPC (TSI model 3775). The measurements show that nucleation increases by around an order of magnitude when the ionization increases from background to supernova levels under fixed gas conditions. The results expand the parameterization presented in Dunne et al. (2016) and Gordon et al. (2017) (for [NH3+ org] Combining double low line 2.2 ppb and T Combining double low line 295 K) to lower sulfuric acid concentrations and higher ion concentrations. The results make it possible to expand the parameterization presented in Dunne et al. (2016) and Gordon et al. (2017) to higher ionization levels.