Abstract
The 1H and 13C NMR signals of cyclohexyl Ph sulfides, sulfoxides, and sulfones were almost completely assigned, and the effects of diastereotopism in cis-4-tert-butylcyclohexyl Ph sulfoxide were rationalized. Substituent effects on the 17O chem. shifts of numerous sulfoxides and sulfones are discussed. An unusual paramagnetic g gauche effect on the 33S nucleus was detected in cis-4-tert-butylcyclohexyl Ph sulfone. [on SciFinder (R)]
Author supplied keywords
- Conformation and Conformers (of cyclohexyl Ph sulf
- Nuclear magnetic resonance (in cyclohexyl Ph sulfi
- carbon 13 NMR sulfide sulfoxide
- diastereotopism sulfide sulfone sulfoxide
- oxygen 17 NMR sulfone
- sulfide cyclohexyl phenyl NMR
- sulfone cyclohexyl phenyl NMR
- sulfoxide cyclohexyl phenyl NMR
- sulfur 33 NMR sulfide sulfone
Cite
CITATION STYLE
APA
Duddeck, H., Korek, U., Rosenbaum, D., & Drabowicz, J. (1986). Proton, carbon-13, oxygen-17 and sulfur-33 NMR investigation of some cyclohexyl phenyl sulfides, sulfoxides, and sulfones. Magnetic Resonance in Chemistry, 24(9), 792–797.
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