PbO as an efficient and reusable catalyst for one-pot synthesis of tetrahydro benzo pyrans and benzylidene malonitriles

Abstract

PbO nanoparticles have been employed as an efficient catalyst for the solvent-free synthesis of tetrahydrobenzo pyrans (yields 81-91%) and benzylidene malonitriles (yields 90-96%) at room temperature using green chemistry approach. PbO nanoparticles were found to be highly efficient, eco-friendly and recyclable heterogeneous catalyst. PbO nanoparticles were prepared by hydrothermal method and characterized by IR, XRD, BET Surface area, SEM, EDAX and TEM with SAED techniques. [Figure not available: see fulltext.] © 2013 Indian Academy of Sciences.