The effect of reactive electric field-assisted sintering of mos2/bi2 te3 heterostructure on the phase integrity of bi2 te3 matrix and the thermoelectric properties

Abstract

In this work, a series of Bi2 Te3/X mol% MoS2 (X = 0, 25, 50, 75) bulk nanocomposites were prepared by hydrothermal reaction followed by reactive spark plasma sintering (SPS). X-ray diffraction analysis (XRD) indicates that the native nanopowders, comprising of Bi2 Te3/MoS2 het-erostructure, are highly reactive during the electric field-assisted sintering by SPS. The nano-sized MoS2 particles react with the Bi2 Te3 plates matrix forming a mixed-anion compound, Bi2 Te2 S, at the interface between the nanoplates. The transport properties characterizations revealed a significant influence of the nanocomposite structure formation on the native electrical conductivity, Seebeck coefficient, and thermal conductivity of the initial Bi2 Te3 matrix. As a result, enhanced ZT values have been obtained in Bi2 Te3/25 mol% MoS2 over the temperature range of 300–475 K induced mainly by a significant increase in the electrical conductivity.