Abstract
Communication: Constitutive equations are derived for enthalpy recovery in glassy polymers after thermal jumps. The model is based on the theory of cooperative relaxation in a version of the trapping concept. It is demonstrated that a critical temperature Tcr and a critical degree of crystallinity fcr exist in a semicrystalline polymer above which structural relaxation vanishes. © WILEY-VCH Verlag GmbH, 2000.
Cite
CITATION STYLE
APA
Drozdov, A. D. (2000). Enthalpy recovery in semicrystalline polymers. Macromolecular Rapid Communications, 21(17), 1238–1243. https://doi.org/10.1002/1521-3927(20001101)21:17<1238::AID-MARC1238>3.0.CO;2-9
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