Early-Age Properties Evaluation of Nano-Metakaolin Cement Paste Based on Electrochemical Impedance Spectroscopy

Abstract

The early-age properties of nano-metakaolin (NMK) cement paste were examined from 15 min to 24 h, contacted between cement and water based on the electrochemical impedance spectroscopy (EIS) method. The effects of a superplasticizer and chloride ions were taken into consideration. The variation of the electrochemical parameters of NMK cement paste with or without the superplasticizer and chloride ions was analyzed. The results demonstrated that the solution resistance and impedance modulus of the cement paste decreased first then increased between 15 min and 12 h after cement contact with water. When the cement contacted with water within about 8 h, the pore solution resistance and impedance modulus were less affected by NMK. When the cement hydration was over about 8 h, the pore solution resistance and impedance modulus of the cement paste were significantly improved by the addition of 1% NMK. The pore solution resistance of the cement paste with 1% NMK was increased by 0.49%, 2.64% and 18.17% as compared with ordinary cement paste when the hydration time was 4 h, 8 h and 12 h, respectively. NMK promoted cement hydration and increased the pore solution resistance and impedance modulus in the cement paste with or without the superplasticizer and chloride ions. The superplasticizer and chloride ions reduced the pore solution resistance and impedance modulus of cement paste with or without NMK.