Efficient activation of coal fly ash for silica and alumina leaches and the dependence of pb(Ii) removal capacity on the crystallization conditions of al‐mcm‐41

Abstract

In this study, four different coal fly ashes (CFAs) were used as raw materials of silica and alumina for the preparation of the alumina‐containing Mobil Composition of Matter No. 41 (Al‐MCM‐41) and the exploration of an activation strategy that is efficient and universal for various CFAs. Alkaline hydrothermal and alkaline fusion activations proceeded at different tempera-tures to determine the best treatment parameters. We controlled the pore structure and surface hydroxyl density of the CFA‐derived Al‐MCM‐41 by changing the crystallization temperature and aging time. The products were characterized by small‐angle X‐ray diffraction, nitrogen isotherms, Fourier‐transform infrared spectroscopy,29Si silica magic‐angle spinning nuclear magnetic reso-nance, and transmission electron microscopy, and they were then grafted with thiol groups to re-move Pb(II) from aqueous solutions. This paper innovatively evaluates the CFA activation strate-gies using energy consumption analysis and determines the optimal activation methodology and parameters. This paper also unveils the effect of the crystallization condition of Al‐MCM‐41 on its subsequent Pb(II) removal capacity. The results show that the appropriate selection of crystallization parameters can considerably increase the removal capacity over Pb(II), providing a new path to tackle the ever‐increasing concern of aquic heavy‐metal pollution.