Site-selective photodeposition of Pt on a particulate Sc-La5Ti2CuS5O7 photocathode: Evidence for one-dimensional charge transfer

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Abstract

Photodeposition of Pt on the Sc-doped La5Ti2CuS5O7 (Sc-LTC) photocathode, a visible-light-responsive semiconducting oxysulfide, is accomplished in a solution containing H2PtCl6 and K2C2O4. Pt particles are selectively deposited on the top surface of rod-like Sc-LTC particles as a result of one-dimensional transfer of photogenerated electrons.

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Ma, G., Liu, J., Hisatomi, T., Minegishi, T., Moriya, Y., Iwase, M., … Domen, K. (2015). Site-selective photodeposition of Pt on a particulate Sc-La5Ti2CuS5O7 photocathode: Evidence for one-dimensional charge transfer. Chemical Communications, 51(20), 4302–4305. https://doi.org/10.1039/c4cc10297e

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