Modified Sol-Gel Processing of NiCr2O4 Nanoparticles; Structural Analysis and Optical Band Gap

Abstract

Nickel Chromite nanoparticles were successfully synthesized via a modified sol-gel method using nickel acetate and ammonium dichromate in melted stearic acid as a complexing agent. The diffractograms of the nanoparticles confirmed a pure formation of NiCr2O4 spinel without any minor phase. The coordination structure of as prepared nanoparticles shows a series of absorption bands below 1,000cm-1 were evidenced the M-O (Cr-O, Ni-O) bond in the sample. Optical band gap, magnetic properties and color parameters (L∗.a∗.b∗) indicates that the final nanoparticles are optically and magnetically active. The particle size of NiCr2O4 was calculated using Scherrer equation at about 24nm. Optical band gap obtained at 1.7eV indicating that NiCr2O4 nanoparticles are semiconductor material and can be used in electrical devices.