Structure and Adsorption Performance of Cationic Entermorpha prolifera Polysaccharide-Based Hydrogel for Typical Pollutants: Methylene Blue, Cefuroxime, and Cr (VI)

Abstract

Hydrogels with polysaccharides as high polymer substrates have surprising advantages in wastewater treatment with complex components. Therefore, in this study, polysaccharides named EPS were extracted from Enteromorpha prolifera, a coastal pollutant with a wide range of sources, and cationic modification was performed to obtain CAEPS, the hydrogel with a double network structure was prepared based on EPS and CAEPS. Meanwhile, the structural characteristic of EPS and CAEPS-based hydrogel were identified by HPLC, AFM, FT-IR, TGA, SEM-EDS, Pore size distribution, and WCA, which showed that the porosity, apparent (skeletal) density, and hydrophilicity of CAEPS-hydrogels. We used nonlinear isotherms to uncover the adsorption mechanism of hydrogel applied to the water environment containing three typical pollutants (Methylene blue, Cefuroxime, and Cr (VI)). The results showed that the adsorption isotherm of the two hydrogels fit the Langmuir isotherm model, which indicated the monolayer adsorption of the pollution factor onto EPS- and CAEPS-hydrogels. The maximum adsorption capacities of CAEPS-hydrogels were higher than EPS-hydrogels, which indicated the microstructure and adsorption performance of the CAEPS-hydrogel are strengthened.