Synthesis of a guanidine NHC complex and its application in borylation reactions

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Abstract

Synthesis of guanidine-linked NHC can be achieved easily through reacting amino-NHC with carbodiimide. Subsequently, guanidine-NHC Ag and Cu complexes were isolated and fully characterized. These Cu complexes are found to be versatile catalysts for hydroboration, semihydrogenation and carboboration of alkynes in a highly stereo- and regioselective fashion. © 2014 The Partner Organisations.

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Tai, C. C., Yu, M. S., Chen, Y. L., Chuang, W. H., Lin, T. H., Yap, G. P. A., & Ong, T. G. (2014). Synthesis of a guanidine NHC complex and its application in borylation reactions. Chemical Communications, 50(33), 4344–4346. https://doi.org/10.1039/c4cc00550c

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