Role of pond sediments for trapping pesticides in an agricultural catchment (Auradé, sw france): Distribution and controlling factors

Abstract

In agricultural areas, ponds are suitable wetland environments to dissipate and reduce the occurrence of pesticides in aquatic environments. However, their impact at a catchment scale is still poorly understood. This study aims to determine how these organic contaminants were trapped in a pond located in an agricultural critical zone from SW France (Auradé catchment). The spatial distribution of pesticide concentrations and their different controlling factors were investigated in waters and sediments collected during two distinct seasons. The results highlighted (i) the link between the presence of the molecules and the agricultural practices upstream, (ii) the influence of hydrological/seasonal conditions, especially on hydrophobic molecule accumulation such as tebuconazole, (iii) the key role of clay content in sediments on the control of moderately hydrophilic pesticides (metolachlor and boscalid), but also the unexpected role of coarse particles for boscalid; and (iv) the influence of sediment depth on pesticide storage. Nevertheless, other physico-chemical parameters, such as mineralogical composition of sediment, needed to be considered to explain the pesticide patterns. This study brings a new hypothesis to be investigated in the future about pesticide behaviour in such pond environments.