Abstract
A 69-membered ring (see picture) results from a metathesis reaction that uses a metalated tris(pincer)-substituted benzene as scaffold. The macrocyclic product can be detached by the addition of Cl after which the template is recovered quantitavely.
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Chuchuryukin, A. V., Dijkstra, H. P., Suijkerbuijk, B. M. J. M., Klein Gebbink, R. J. M., Van Klink, G. P. M., Mills, A. M., … Van Koten, G. (2003). Macrocycle synthesis by olefin metathesis on a nanosized, shape-persistent tricationic platinum template. Angewandte Chemie - International Edition, 42(2), 228–230. https://doi.org/10.1002/anie.200390086
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