Film formation of latex

Abstract

Latex film formation, the process by which an aqueous dispersion of polymer particles is transformed into a continuous material, has a direct bearing on the final film morphology and properties. Each of the primary stages of film formation (evaporative drying and ordering; particle deformation; and polymer interdiffusion) have been studied experimentally. Recently-developed non-invasive techniques, including direct nonradiative energy transfer, atomic force microscopy, small angle neutron scattering, environmental scanning electron microscopy, and various optical techniques have greatly enhanced the study of these stages. Even so, the exact cause (or causes) of particle deformation is still a topic of considerable debate. Several factors are experimentally known to influence latex film formation: the ambient conditions; the presence of surfactants, plasticizers and pigments; and latex particle structure. An important aim in the study of latex film formation is to understand the mechanisms by which these and other factors affect the process. New challenges lie in the study of film formation of core-shell latices, latex blends and new compositions. © 1997 Elsevier Science S.A.