Preparation of Isopropyl Acrylamide Grafted Chitosan and Carbon Bionanocomposites for Adsorption of Lead Ion and Methylene Blue

Abstract

Wastewater, which is rich with heavy elements, dyes, and pesticides, represents one of the most important environmental pollutants. Thus, it has been significant to fabricate environmentally friendly polymers with high adsorption ability for those pollutants. Herein, crosslinked chitosan (C-Cs) was prepared using isopropyl acrylamide and methylene bisacrylamide. Carbon nanoparticles (C-NPs) were also obtained by the treatment of the agricultural wastes, which was used with C-Cs to prepare C-Cs/C-NPs nanocomposite (C-Cs/C-NC). Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and transmission electron microscope (TEM) were used to investigate the prepared adsorbent. C-Cs, C-NPs, and C-Cs/C-NC were used in water treatment for the adsorption of lead ions (Pb+2) and methylene blue (MB). The adsorption process occurred by the prepared samples was investigated under different conditions, including contact time, as well as different doses and concentrations of adsorbents. The findings exhibited that the adsorption of Pb+2 and MB by C-Cs/C-NC was higher than C-Cs and C-NPs. In addition, the kinetic and isotherm models were studied, where the results showed that the adsorption of Pb+2 and MB by various adsorbents obeys pseudo-second-order and Langmuir isotherms, respectively.