Ice Regelation: Hydrogen-bond extraordinary recoverability and water quasisolid-phase-boundary dispersivity

Abstract

Regelation, i.e., ice melts under compression and freezes again when the pressure is relieved, remains puzzling since its discovery in 1850's by Faraday. Here we show that hydrogen bond (O:H-O) cooperativity and its extraordinary recoverability resolve this anomaly. The H-O bond and the O:H nonbond possesses each a specific heat ηx (T/Dx) whose Debye temperature Dx is proportional to its characteristic phonon frequency ωx according to Einstein's relationship. A superposition of the ηx (T/Dx) curves for the H-O bond (x=H, ωH ∼3200cm -1) and the O:H nonbond (x=L, ωL ∼200cm -1, DL =198K) yields two intersecting temperatures that define the liquid/quasisolid/solid phase boundaries. Compression shortens the O:H nonbond and stiffens its phonon but does the opposite to the H-O bond through O-O Coulomb repulsion, which closes up the intersection temperatures and hence depress the melting temperature of quasisolid ice. Reproduction of the T m (P) profile clarifies that the H-O bond energy E H determines the T m with derivative of E H =3.97eV for bulk water and ice. Oxygen atom always finds bonding partners to retain its sp 3 -orbital hybridization once the O:H breaks, which ensures O:H-O bond recoverability to its original state once the pressure is relieved.