Abstract
The zinc hydridotriphenylborates [(L)Zn(TMDS)][HBPh3] and [(L)ZnX][HBPh3] (L = Me4TACD, Me4[12]aneN4; TMDS = N(SiHMe2)2; X = Cl, Br, I) were synthesized by BPh3-mediated β-SiH abstraction and salt metathesis with KHBPh3, respectively. CO2 is rapidly inserted into the B-H bonds. [(L)Zn(TMDS)][HBPh3] catalyzes the hydroboration of polar substrates including CO2.
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CITATION STYLE
APA
Mukherjee, D., Wiegand, A. K., Spaniol, T. P., & Okuda, J. (2017). Zinc hydridotriphenylborates supported by a neutral macrocyclic polyamine. Dalton Transactions, 46(19), 6183–6186. https://doi.org/10.1039/c7dt01094j
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