Forced-flow liquid chromatography with a coulometric detector

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Abstract

A tubular platinum electrode packed with small chips of platinum is described which was shown to function with 100% electrolytic efficiency. Application of the electrode is described for the coulometric determination of electroactive species in the effluent from a liquid chromatograph. Cu and Fe were determined in a series of standards. An average relative deviation of less than 2 ppt was obtained for analysis of samples containing 5 μg of Cu(II) and 5 μg of Fe(III). © 1973.

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Johnson, D. C., & Larochelle, J. (1973). Forced-flow liquid chromatography with a coulometric detector. Talanta, 20(10), 959–971. https://doi.org/10.1016/0039-9140(73)80004-9

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