Correction to “100th Anniversary of Macromolecular Science Viewpoint: Polymerization of Cumulated Bonds: Isocyanates, Allenes, and Ketenes as Monomers”

Abstract

Polymer chemistry offers exciting opportunities to tailor the properties of soft materials through control of the composition of the polymers and their interaction with each other, additives, and surfaces. Ongoing advances in the synthesis of polymeric materials demonstrate the drive for materials with tailored properties for enhanced performance in the next generation of materials and devices. One class of small molecules that can serve as monomers in chain growth polymerization are cumulated double bonds of the general form X═Y═Z. The three most common classes of these molecules are isocyanates (N═C═O), allenes (C═C═C), and ketenes (C═C═O), each of which has been explored as monomers under a variety of conditions. The orthogonality of the two pi bonds of the cumulated double bonds (i.e., lack of conjugation) enables the formation of different polymer backbones from a single monomer, provided the regioreactivity is controlled. This Viewpoint outlines the use of these three cumulated double bonds as monomers,