Abstract
(Figure Presented) The carbon-phosphorus-antimony cage of P 2C2tBu2SbCl (see picture) adopts an envelope-type structure which is quite distinct from its phosphorus analogue, the tricyclic compound P2C2tBu2PCl. DFT calculations reveal that subtle changes in electronic structure as a result of the inert-pair effect lead to profound differences in structural and dynamic behavior. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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Fish, C., Green, M., Jeffery, J. C., Kilby, R. J., Lynam, J. M., McGrady, J. E., … Willans, C. E. (2006). A main-group analogue of housene: The subtle influence of the inert-pair effect in group 15 clusters. Angewandte Chemie - International Edition, 45(40), 6685–6689. https://doi.org/10.1002/anie.200601804
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