Palladium-catalyzed oxidative acyloxylation/carbocyclization of allenynes

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Abstract

New bonds: The title reaction provides access to synthetically useful acyloxylated vinylallenes where a new C-C bond, a new C-O bond, and a new allene structure are formed. Furthermore, an aerobic version of this transformation was realized using catalytic amounts of p-benzoquinone (BQ) together with catalytic amounts of cobalt salophen. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Deng, Y., & Bäckvall, J. E. (2013). Palladium-catalyzed oxidative acyloxylation/carbocyclization of allenynes. Angewandte Chemie - International Edition, 52(11), 3217–3221. https://doi.org/10.1002/anie.201208718

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