Salen supported Al-O-CP and Ga-PCO complexes

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Abstract

The first OCP adducts of aluminium and gallium are reported. The complexes are supported by sterically encumbered salen ligands and reveal a selective binding to O and P, respectively. Their reactivity with diazaphosphenium Lewis acids and N-heterocyclic carbene Lewis bases is described, in addition to cycloaddition reactions with s-tetrazines.

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Mei, Y., Borger, J. E., Wu, D. J., & Grützmacher, H. (2019). Salen supported Al-O-CP and Ga-PCO complexes. Dalton Transactions, 48(13), 4370–4374. https://doi.org/10.1039/c9dt00485h

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