Heteroatom-doped carbon nanostructures derived from conjugated polymers for energy applications

Abstract

Heteroatom-doped carbon materials have been one of the most remarkable families of materials with promising applications in fuel cells, supercapacitors, and batteries. Among them, conjugated polymer (CP)-derived heteroatom-doped carbon materials exhibit remarkable electrochemical performances because the heteroatoms can be preserved at a relatively high content and keep stable under harsh working conditions. In this review, we summarized recent advances in the rational design and various applications of CP-derived heteroatom-doped carbon materials, including polyaniline (PANI), polypyrrole (PPy), and their ramification-derived carbons, as well as transition metal-carbon nanocomposites. The key point of considering CP-derived heteroatom-doped carbon materials as important candidates of electrode materials is that CPs contain only nonmetallic elements and some key heteroatoms in their backbones which provide great chances for the synthesis of metal-free heteroatom-doped carbon nanostructures. The presented examples in this review will provide new insights in designing and optimizing heteroatom-doped carbon materials for the development of anode and cathode materials for electrochemical device applications.