Abstract
The palladium catalysed Mizoroki-Heck, Suzuki-Miyaura and Sonogashira reactions were successfully carried out under irradiation with sunlight. The Heck reaction gives considerable amount of Z product due to photochemical isomerization of initially formed E alkenes. Reaction of methyl 2-iodobenzoate with acrylamide under solar condition furnished 2H-2-benzazepine-1,3-dione rather than the expected derivative of cinnamate while the same reaction with ethyl 2-iodobenzoate gave the desired cinnamide. © 2012 Elsevier Ltd. All rights reserved.
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Chaudhary, A. R., & Bedekar, A. V. (2012). Sunlight promoted palladium catalysed Mizoroki-Heck, Suzuki-Miyaura and Sonogashira reactions. Tetrahedron Letters, 53(45), 6100–6103. https://doi.org/10.1016/j.tetlet.2012.08.139
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