Crystal structure of N-[3-(2-chlorobenzoyl)-5-ethylthiophen-2-yl]-2-[(E)-(2-hydroxybenzylidene)amino]acetamide

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Abstract

In the title compound, C22H19ClN2O3S, the dihedral angle between the mean planes of the thiophene ring and the chlorophenyl and hydroxyphenyl rings are 70.1 (1) and 40.2 (4)°, respectively. The benzene rings are twisted with respect to each other by 88.9 (3)°. The imine bond lies in an E conformation. Intramolecular O - N and N - O hydrogen bonds each generate S(6) ring motifs. In the crystal, weak C - O interactions link the molecules, forming chains along the c axis and zigzag chains along the b axis, generating sheets lying parallel to (100).

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Kaur, M., Jasinski, J. P., Kavitha, C. N., Yathirajan, H. S., & Byrappa, K. (2014). Crystal structure of N-[3-(2-chlorobenzoyl)-5-ethylthiophen-2-yl]-2-[(E)-(2-hydroxybenzylidene)amino]acetamide. Acta Crystallographica Section E: Structure Reports Online, 70(9), o1011–o1012. https://doi.org/10.1107/S1600536814018224

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