Investigations on the redox character of dithizone by voltammetric methods. Part I.The reduction of dithizone in aqueous solutions

Abstract

The mechanism of the electrochemical reduction of dithizone to the corresponding hydrazo compound, diphenylthiocarbazide, has been examined in detail by polarographic and voltammetric techniques over a wide pH range. The reaction is reversible and dithizone can be determined polarographically in the range 10-3-10-5 M. This polarographic behaviour suggests new applications of dithizone as an electroanalytical reagent. © 1974.