Abstract
The first stable bromoallene oxides were obtained by the DMDO epoxidation of 1-bromo-1,3-di-tert-alkylallenes, producing the first crystalline allene oxide of any kind. The epoxidations are regioselective for the bromine-bearing Δ1,2 alkene, and also face selective producing single diastereomer E-olefin products.
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CITATION STYLE
APA
Christopher Braddock, D., Mahtey, A., Rzepa, H. S., & White, A. J. P. (2016). Stable bromoallene oxides. Chemical Communications, 52(75), 11219–11222. https://doi.org/10.1039/c6cc06395k
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