Study of the Sedimentation Parameters of an Iron Ore Tailing from Fundão Dam Using a Tannin-Based Coagulant

Abstract

From the rupture of the Fundão dam in Mariana–MG, there are tailings still present at the bottom of the plant that must be recovered. The flocculation followed by sedimentation operation can be applied as a unit operation in this recovering process. Instead of using conventional inorganic coagulants, bio-based coagulants offer some advantages, due to their low toxicity and biodegradability. Nonetheless, the use of bio-based coagulants in the mining industry is not established yet, due to the complex parameters that must be taken in consideration. This study analyzes the influence of the pH and flocculant concentration, which are the variables of the 22 full factorial design. The pH value for the batch sedimentation process was defined ranging from 5 to 9. Tanfloc, a tannin-based coagulant, was used as a coagulant agent. The results indicate a strong dependence on the coagulant concentration, and a recommended 15 g/L dosage with pH varying from 6 to 8. From batch sedimentation, it was possible to determine an exponential model for the sedimentation with an excellent fitting (R2 = 0.997). The sedimentation efficiency calculated is 65.6%. These results confirm the potential use of bio-based materials in mining tailing treatments. In addition, they can be used in equipment sizing and simulations of the sedimentation operation.